BIO4Africa research publications

The BIO4Africa partners are conducting a wide range of research studies. The objective is to investigate the nutritional potential and functional properties of agricultural waste products and the optimal setup and processing steps for bio-based technologies in local contexts. These findings are then used to optimise the pilot trials at our test sites.

Here you can find an overview of the studies that have been published in international journals to date. Click on the images to view the literature.

Hydrothermal carbonization of Typha australis: Influence of stirring rate

Omar M. Abdeldayem, Md Abdullah Al Noman, Capucine Dupont, David Ferras, Lat Grand Ndiaye, Maria Kennedy. Environ Res. 2023 Nov 1;236(Pt 2):116777. doi: 10.1016/j.envres.2023.116777. Epub 2023 Jul 28. PMID: 37517487.

 

Abstract

According to existing literature, there are no conclusive results on the impact of stirring on hydrothermal carbonization (HTC); some studies report a significant impact on the product's properties, while others indicate no influence. This study investigates the influence of stirring rate on several responses and properties of HTC products, including solid mass yield, solid carbon fraction, surface area, surface functional groups, morphology, and the fate of inorganic elements during HTC. Waste biomass was introduced as a feedstock to a 2 L HTC reactor, where the effects of temperature (180-250 °C), residence time (4-12 h), biomass to water (B/W) ratio (1-10%), and stirring rate (0-130 rpm) were investigated. The findings of this study conclusively indicated that the stirring rate does not influence any of the studied responses or properties of hydrochar under the selected experimental conditions used in this study. Nevertheless, the results indicated that a low-stirring rate (5 RPM) is enough to slightly enhanced the heating-up phase of the HTC reactor. For future research, it is recommended to examine the impact of stirring rate on the HTC of other types of biomass using the methodology developed in this study.

 

 

Reconsidering lab procedures for hydrothermal carbonization of biomass: The impact of pre-drying and stirring

Omar M. Abdeldayem, Capucine Dupont, David Ferras, Lat Grand Ndiaye, Maria Kennedy. Journal of Analytical and Applied Pyrolysis. Volume 179, 2024. 106459, ISSN 0165-2370.
https://doi.org/10.1016/j.jaap.2024.106459.

Abstract

Although industrial hydrothermal carbonization (HTC) uses wet feedstock, lab-scale studies tend to dry the feedstock under the assumption that the rehydration of the feedstock would restore its original properties. To the best of our knowledge, this assumption has not been thoroughly examined at the lab scale; therefore, its investigation is crucial to prevent any discrepancies that might affect the upscaling of HTC. This research aims to examine the effects of pre-drying biomass by comparing it to the use of wet biomass in HTC experiments, employing three different types of biomass (rejected tomatoes, rejected apples, and digestate). Additionally, the study investigates the influence of stirring on pre-dried and wet biomass under the selected HTC conditions. The results indicate a substantial disparity in studied hydrochar properties when using pre-dried biomass compared to wet biomass. For pre-dried biomass, there is a tendency for an increase in mass yield and solid carbon yield in most examined samples (5–10% dry basis) compared to the wet biomass. Regarding functional groups, wet tomatoes and apples exhibit more pronounced peaks than pre-dried samples. Conversely, digestate shows similar spectra across all examined scenarios. The effect of stirring appears insignificant for most of the studied scenarios; nevertheless, it reduced dehydration and decarboxylation reactions during HTC. 

 

Biochars from slow pyrolysis of peanut shells, cashew nut shells and millet stalks as value-added products for briquette production

Philippe Bernard Himbane and Lat Grand Ndiaye. Biochars from slow pyrolysis of peanut shells, cashew nut shells and millet stalks as value-added products for briquette production. Int. J. of Adv. Res. Jan 2024. 1210-1220 (ISSN 2320-5407). http://dx.doi.org/10.21474/IJAR01/18238

Abstract

Biomass is nowadays used for producing biochar briquettes through slow pyrolysis technologies, namely for cooking purposes in developing countries. This article investigated some properties of biochar obtained from tropical biomasses like peanut shells, cashew nut shells, and millet stalks, pyrolysed at 400°C and 800°C. Firstly the mass yield and energy yield of the biochar were determined. The main properties investigated were obtained by conducting proximate and ultimate analysis, determination of calorific value, FTIR (Fourier-transform infrared) analysis and thermogravimetric analysis. The results showed that, depending on the biomass and the pyrolysis temperature, the biochar yields varied from 20.26% to 42.79% while the energy yields varied from 24.24% to 60.71%. The highest yields are obtained with the lowest temperature and are all more important with peanut shells. All the biochars had fixed carbon contents greater than 60%, except biochar obtained at 400°C with millet stalks. The millet stalk biochar obtained at 400°C had the highest ash content (21.41%) and the lowest fixed carbon content (59.31%). It was observed that the more the pyrolysis temperature increased, the more the carbon content increased. The lower heating value of raw biomasses and biochars varied respectively between 18.36 and 22.51 MJ/kg and between 23.83 and 30.85 MJ/kg. FTIR analysis results showed that the O-H and C-O bonds disappeared in the case of biochars obtained at 800°C. The reactivity of biochars towards O2 showed that, for all biochars, ignition temperatures (Ti) were up to 317°C and the temperatures at maximum mass loss rate were between 438°C and 501°C.

Activation kinetics of biochars from peanut shells, cashew nut shells, and millet stalks under isothermal conditions in CO2 atmosphere

Philippe Bernard Himbane and Lat Grand Ndiaye. Activation kinetics of biochars from peanut shells, cashew nut shells, and millet stalks under isothermal conditions in CO2 atmosphere. South African Journal of Chemical Engineering. Vol. 49, 2024. Pages 249-257 ISSN 1026-9185. https://doi.org/10.1016/j.sajce.2024.06.004.

Abstract

This study investigates the reactivity kinetics of biochar from biomass. The biochars were obtained by pyrolysing peanut shells, cashew nut shells and millet stalks at 800°C in a fixed bed reactor. The chemical composition of the biochar samples shows that silicon, potassium and magnesium are the major elements in the biochar of peanut shells, while potassium and magnesium are the major elements in the biochar of cashew nut shells and millet stalks. The biochars were activated in a CO2 (200 Nml/min) atmosphere at temperatures 1123 K, 1173 K, and 1223 K under atmospheric pressure. The random pore model (RPM) and a modified random pore model (MRPM) were used to correlate the reactivity profiles versus carbon conversion and to determine the kinetic parameters. It was observed that biochar reactivity increases as the temperature increases, attaining at least three times at 1173 K than those corresponding to 1123 K. Furthermore, the increase in reactivity is more pronounced with millet stalk biochar. It was observed that the RPM model cannot follow the kinetic of the experimental reactivity of all biochar samples. However, a better fitting of the reactivity is obtained using the MRPM model. The activation energies (Ea) are distributed in the range of 98.11–148.46 kJ/mol while the pre-exponential factors (k0) are in the range of 19.31–249.53 s-1. It was observed that, for the MRPM model, the lower activation energy and lower pre-exponential factor were obtained by the cashew nut shell biochar. However, Ea and k0 are well evaluated for peanut shell and millet stalk biochar with a coefficient of determination of 99.76%. The proposed modified random pore model could be used to describe the reactivity of biochar from biomass as well as the reactivity of coal.

Studies of gas emissions and performance of stoves using biomass char briquettes

Tessembou Biaye, Philippe Bernard Himbane and Lat Grand Ndiaye. Studies of gas emissions and performance of stoves using biomass char briquettes. Journal of Materials Science and Engineering A 14 (4-6) 2024. Pages 35-48. doi: 10.17265/2161-6213/2024.4-6.001

Abstract

In this article, we evaluated the energy performance parameters and gas emissions to identify which of the stoves studied performs best and the biomass char briquettes with lowest emissions. Biomass char briquettes from peanut shells, cashew nut shells and corn cobs were produced using wheat flour as a binder. The binder rate was set at 9% and 10%. Based on the energy performance parameters, it was highlighted that the char briquette from corn cob with 9% binder has the best energy performance, followed by the char briquette from peanut shells with 9% binder and, lastly, the char briquette from cashew nut shells with 10% binder. The average energy efficiency of the 'jambar' stove was 15.68%, while that of the 'Malgache' stove was 12.41%. The average specific fuel consumption of the jambar stove was 0.12kg per kilogram of water while that of the Malgache stove was 0.15kg per kilogram of water. In terms of gaseous emissions, CO (carbon monoxide) concentrations were very high for char briquettes from corn cobs, with a CO emission factor of 0.40g/min and NOx emission factor of 9.79mg/min. For char briquettes from cashew nut shells, CO and NOx emission factors were respectively 0.30g/min and 5.32mg/min. The lowest average concentrations were obtained with char briquettes from peanut shells with a CO emission factor of 0.25g/min and NOx 3.98mg/min.

Co-designing sustainable biochar business models with sub-Saharan African communities for inclusive socio-economic transformation

Mohammed, S., Fatumah, N., Abasi, K. et al. Co-designing sustainable biochar business models with sub-Saharan African communities for inclusive socio-economic transformation. Sci Rep 14, 15802 (2024). https://doi.org/10.1038/s41598-024-66120-y

Abstract

Smallholder farmers in sub-Saharan Africa (SSA) encounter multiple livelihood challenges. Embracing circular bioeconomy principles, particularly considering agricultural and food processing residues, could enable inclusive, locally led, sustainable development pathways within rural communities. Biochar products are one such example of a bio-based material that can be generated using circular principles and deployed for sustainable community development, including among smallholder farmers. This research leverages empirical evidence from four SSA regions to explore the potential of inclusive and sustainable biochar business models, namely: (i) Northern Region, Ghana, (ii) Yamoussoukro, Côte d’Ivoire, (iii) Casamance, Senegal, and (iv) Western Region, Uganda. Co-creation workshops using the Triple-Layered Business Model Canvas framework were carried out in each region with local stakeholders to evaluate the social, ecological, and economic implications of four locally relevant biochar applications: water filtration, biogas purification, soil amendment, and cooking fuel briquettes. Data was analysed at an aggregate level for all regions and applications. The study describes this consolidated biochar business model and examines the implications for SSA communities. The resulting sustainable bio-based business model can guide value chain actors and policymakers in SSA communities towards rural sustainable development with a better understanding of the needs, opportunities, challenges, and impacts of biochar-based value chain development.